An update,
As covered in probewin manual you can then set up an empircal correction. Entering the intercept and slope for each spectrometer/bias/crystal into emppha.dat
Then when adding elments you can click calculate empirical pha - it will calculate it where intercepts and slopes have been added for that spectrometer, crystal & bias - check using desired bias before clicking
In probewin.ini can set UseEmpiricalPHADefaults=1