One subject that has never been discussed on the forum is synthesis of sulfides, sulfosalts, arsenides, selenides, tellurides, and other compounds commonly found in ore deposits. Many of the binary compounds are relatively easy to synthesize in a muffle furnace in silica glass capsules. I’ve made a variety of such compounds – excluding sulfides – using a crude open capsule technique and B2O3 flux (must be dehydrated!). However, I don’t have the resources or skill necessary to produce many of the compounds I need. For instance, I’d love to have a set of the diarsenides and sulfarsenides of Co, Ni, and Fe (apparently arsenopyrite is difficult to synthesize, though).
Presumably others out there must have a similar interest??