The problem is the proximity of the K and Cl peaks. As with WDS, measuring the background is critical to measuring the peak intensity with utmost accuracy. In DTSA-II, measuring the background on a standard requires about one FWHM on each side of the peak. (Note at this isn't true about unknowns because a high quality peak shape reference allows us to deconvolve even the nastiest interferences.) While the K and Cl peaks are separated, they are not sufficiently separated. You will need "peak shape references" to fit these peaks - table salt (NaCl) while not a good standard makes an excellent Cl reference. For K, either KBr or KAlSi3O8 can be used as a reference.
Remember, a reference does not need to meet some of the requirements of a standard - it needn't be absolutely stable under the beam and it needn't be prepared with the same care (surface finish, topography) and you don't need to know the exact composition (just which elements are present). Thus materials like grains of table salt can be used as a reference for Na or Cl while they are less well suited to be used as a standard.